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How Are Super Capacitors Different From Electrolytic Capacitors

learnelectronics 3,816 lượt xem 1 year ago
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How Are Super Caps Different From Electrolytic Caps

The electrolyte forms an ionic conductive connection between the two electrodes which distinguishes them from conventional electrolytic capacitors where a dielectric layer always exists, and the so-called electrolyte, e.g., MnO2 or conducting polymer, is in fact part of the second electrode (the cathode, or more correctly the positive electrode). Supercapacitors are polarized by design with asymmetric electrodes, or, for symmetric electrodes, by a potential applied during manufacturing.
Double-layer capacitance – electrostatic storage of the electrical energy achieved by separation of charge in a Helmholtz double layer at the interface between the surface of a conductor electrode and an electrolytic solution electrolyte. The separation of charge distance in a double-layer is on the order of a few ångströms (0.3–0.8 nm) and is static in origin.[15]
Pseudocapacitance – Electrochemical storage of the electrical energy, achieved by redox reactions, electrosorption or intercalation on the surface of the electrode by specifically adsorbed ions, that results in a reversible faradaic charge-transfer on the electrode.[15]
Double-layer capacitance and pseudocapacitance both contribute inseparably to the total capacitance value of a supercapacitor.[22] However, the ratio of the two can vary greatly, depending on the design of the electrodes and the composition of the electrolyte. Pseudocapacitance can increase the capacitance value by as much as a factor of ten over that of the double-layer by itself.[11][27]

Electric double-layer capacitors (EDLC) are electrochemical capacitors in which energy storage predominantly is achieved by double-layer capacitance. In the past, all electrochemical capacitors were called "double-layer capacitors". Contemporary usage sees double-layer capacitors, together with pseudocapacitors, as part of a larger family of electrochemical capacitors[11][27] called supercapacitors. They are also known as ultracapacitors.

Supercapacitors, Super Capacitor, Science, Technology, Capacitor Types, Guide, Tantalum Capacitor, Edlc, Power, Ultracapacitor

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